这篇研究通过实验与理论计算相结合，揭示了多金属氧酸盐（POM）[PW11O39Zn(H2O)]5?在无卤条件下催化CO2与环氧化物环加成反应的新机制。研究发现，Zn中心通过类似碳酸酐酶（CA）的作用活化CO2形成HCO3?中间体，进而分步催化生成环状碳酸酯（CyCarb）。该工作为绿色 ...

Transition metal phosphides are known to be promising materials for batteries and catalysts. However, the synthesis of their single crystals is difficult. Recently, researchers from Hanyang University ...